Redox control of a polymerization catalyst by changing the oxidation state of the metal center.
نویسندگان
چکیده
The activity of cerium alkoxide complexes supported by a Schiff base ligand was controlled using redox reagents during the ring-opening polymerization of L-lactide. The rate of L-lactide polymerization was modified by switching in situ between the cerium(III) and cerium(IV) species.
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ورودعنوان ژورنال:
- Chemical communications
دوره 47 35 شماره
صفحات -
تاریخ انتشار 2011